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Yogita Ingle 5 years, 8 months ago
Most of the dirt is oily in nature and oil does not dissolve in water. The molecule of soap constitutes sodium or potassium salts of long-chain carboxylic acids. In the case of soaps, the carbon chain dissolves in oil and the ionic end dissolves in water. Thus the soap molecules form structures called micelles. In micelles, one end is towards the oil droplet and the other end which is the ionic faces outside. Therefore, it forms an emulsion in water and helps in dissolving the dirt when we wash our clothes.
Soaps are sodium or potassium salts of long-chain fatty acids. Hard water contains calcium and magnesium ions. When soaps are dissolved in hard water, these ions displace sodium or potassium from their salts and form insoluble calcium or magnesium salts of fatty acids. These insoluble salts separate as scum.
This is the reason why soaps do not work in hard water.
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