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Ether is not miscible in water because it cannot form H-bonds with water. However lower members of ethers are soluble in water. The solubility of ethers decreases from lower members to higher members due to increase in size of alkyl group which decreases the formation of hydrogen bonds with water.
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Use of integrated rate equation:
- The value of rate constant can be known when concentration of reactant at different times are known.
- Order of a reaction can be determined by the knowledge of reaction concentration at different times.
Posted by Alok Kumar Shah 6 years, 5 months ago
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A meso compound contains at least two stereogenic centers, yet the molecule itself is not chiral. This is because meso compounds contain an internal plane of symmetry; the molecule can be split by an imaginary mirror so that all atoms on one side of the mirror are the exact reflection of the atoms on the other side. This can be seen below for cis-1,2-dimethylcyclopentane; there are two chiral centers in the molecule since the two carbons labeled with the red asterisk are each bonded to four different groups. A mirror placed through the molecule, along the plane indicated by the dashed line, will exactly bisect the molecule with all groups exactly reflected by their counterparts on the other side of the "mirror".
Posted by Alok Kumar Shah 6 years, 5 months ago
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To be miscible with water, the solute-water force of attraction must be stronger than the solute-solute and water-water forces of attraction. Alkyl halides are polar molecules and so held together by dipole-dipole interactions. Similarly, strong H-bonds exist between the water molecules. The new force of attraction between the alkyl halides and water molecules is weaker than the alkyl halide-alkyl halide and water-water forces of attraction. Hence, alkyl halides (though polar) are immiscible with water.
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You need to go to 'Test Series' on mycbseguide app/dashboard.
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Lithium has smaller size and therefore, high polarizing power. Therefore, lithium compounds has covalent character which is responsible for their solubility in pyridine (non-polar solvent).
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Aromatic Hydrocarbons are circularly structured organic compounds that contain sigma bonds along with delocalized pi electrons. They are also referred to as arenes or aryl hydrocarbons.
A few examples of aromatic hydrocarbons are provided below. It can be observed that all these compounds contain a benzene ring.
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Acyl chloride (acid chloride) is hydrogenated over catalyst, palladium on barium sulphate. This reaction is called Rosenmund reduction.

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