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Why para-nitro phenol have higher boiling …

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Why para-nitro phenol have higher boiling point than ortho-nitro phenol?
  • 2 answers

Rohan Kumar 5 years, 6 months ago

?

G K 5 years, 6 months ago

O-nitrophenol undergoes ?INTRAMOLECULAR?Hydrogen bonding (within molecule).....and it can be easily separated during heating since it doesn't have any major interaction with other molecules near by.....hence less bpt.... P-nitrophenol undergoes ?INTERMOLECULAR? Hydrogen bonding...... It interacts with atoms of different molecules near by and increase its boiling point.....
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