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Haloalkanes react with KNO2 to form …

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Haloalkanes react with KNO2 to form alkyl isonitrite. But with AgNO2 it forms alkyl nitrite. Explain why?

    • Posted by Ibrahim Shaikh 7 years, 5 months ago

    CBSE > Class 12 > Chemistry
    • 1 answers

    Rishabh Sahu 7 years, 5 months ago

    KNO2 is ionic molecule but AgNO2 has covalent character from fajan's rule as here Ag+ has pseudo noble gas configuration or filled inner d shell.

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