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Haloalkanes react with KNO2 to form …

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Haloalkanes react with KNO2 to form alkyl isonitrite. But with AgNO2 it forms alkyl nitrite. Explain why?
  • 1 answers

Rishabh Sahu 5 years, 10 months ago

KNO2 is ionic molecule but AgNO2 has covalent character from fajan's rule as here Ag+ has pseudo noble gas configuration or filled inner d shell.
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