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Why in [Ni (Nh3)6]+2 pairingof electron …

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Why in [Ni (Nh3)6]+2 pairingof electron doesnot takes place while drawing its structure using VBT??

Posted by Abhi Aahi 6 years, 9 months ago

CBSE > Class 12 > Chemistry

3 answers

Ruby Bajwa 6 years, 9 months ago

BTW NH3 is a strong ligand.

1Thank You

Ruby Bajwa 6 years, 9 months ago

It is impossible that one of the inner d orbital and one of the outer d orbital are used as hybrid orbitals. As in +2 state of Ni only one d orbital is vacant after pairing thus it isn't possible to have dsp3d hybridization, thus no pairing occurs and we get complex with hybrid orbitals in outer d orbital thus sp3d2 hybridization is attained.

1Thank You

Go Pi 6 years, 9 months ago

NH3 Is a weak ligand. so pairing OF ELECTRONS doesnt take place

0Thank You

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Give reason. Boiling point of ethyl bromide 3higher than that of ethyl chloride?

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