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A mixture of chlorobenzene & bromobenzene …

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A mixture of chlorobenzene & bromobenzene is nearly an ideal solution but a mixture of chloroform & acetone is not. explain?

Posted by Ruhana Parvin 1 year, 6 months ago

CBSE > Class 12 > Chemistry

1 answers

Anjan Karthi 1 year, 6 months ago

In chloroform and acetone mixture, the double bonded oxygen of acetones get hydrogen bonded with the hydrogen of chloroform. Thus, there is a significant change in the strength of bonding in chloroform - acetone mixtures, than in individual chloroform and acetone solutions. Thus, vapour pressure also changes during dissolution and consequently, the solution does not follow Raoul's law for ideal solutions.

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