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Arrange the following compounds in increasing …

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Arrange the following compounds in increasing order of their acid strength with reason Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol, phenol, 4-methylphenol.???

Posted by Kirti Sharma? 3 years, 6 months ago

CBSE > Class 12 > Chemistry

1 answers

Arman Gupta 3 years, 6 months ago

PROPAN-1-OL <<< 4-METHYL PHENOL <<< PHENOL <<< 3-NITROPHENOL <<< 3,5-DINITROPHENOL <<< 2,4,6-TRINITROPHENOL... THIS IS BECAUSE ALCHOHOL IS ALWAYS LESS ACIDIC THAN PHENOLS... ALSO NITRO GROUP AT META POSITIONS WITHDRAWS ELECTRONS ONLY BY INDUCTIVE EFFECT AND AT PARA POSITIONS WITHDRAW ELECTRONS BY REASONANCE AS WELL AS INDUCTIVE EFFECT...FINALLY METHY GROUP IS AN ELECTRON DONATING GROUP WHICH INCREASES ELECTRON DENSITY ON OXYGEN AND THUS REDUCES THE ACIDITY...

2Thank You

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