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When a coordination compound NiCl2. 6H2O …

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When a coordination compound NiCl2. 6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the compound (ii) IUPAC name of the compound

Posted by Mr. King 3 years, 11 months ago

CBSE > Class 12 > Chemistry

1 answers

Gaurav Seth 3 years, 11 months ago

When the co-ordination compound is reacted with AgNO3 it liberates 2 moles of AgCl, which indicates 2 Cl- ions are outside the co-ordination sphere satisfying primary valence(+2).
- Remaining 6 H2O ligands will be inside the co-ordination sphere satisfying secondary valence (+6)
- Therefore, structural formula of the compound must be [Ni(H2O)6]Cl2.

3Thank You

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