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Write vanderwaals equation

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Write vanderwaals equation
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सत्य सनातन? 4 years, 5 months ago

Thanks

Yogita Ingle 4 years, 5 months ago

Van der Waals equation is an equation relating the relationship between the pressure, volume, temperature, and amount of real gases. For a real gas containing ‘n’ moles, the equation is written as;

(P+an2V2)(Vnb)=nRT(P+V2an2)(Vnb)=nRT

Where, P, V, T, n are the pressure, volume, temperature and moles of the gas. ‘a’ and ‘b’ constants specific to each gas.

The equation can further be written as;

  1.  Cube power of volume: V3(b+RTP)V2+aPVabP=0V3(b+PRT)V2+PaVPab=0
  2. Reduced equation (Law of corresponding states) in terms of critical constants:

(π+3φ2)(3φ1)=8τ:whereπ=PPc,φ=VVcandτ=TTc(π+φ23)(3φ1)=8τ:whereπ=PcP,φ=VcVandτ=TcT

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