Write vanderwaals equation
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Posted by सत्य सनातन? 4 years, 5 months ago
- 2 answers
Yogita Ingle 4 years, 5 months ago
Van der Waals equation is an equation relating the relationship between the pressure, volume, temperature, and amount of real gases. For a real gas containing ‘n’ moles, the equation is written as;
(P+an2V2)(V−nb)=nRT(P+V2an2)(V−nb)=nRT
Where, P, V, T, n are the pressure, volume, temperature and moles of the gas. ‘a’ and ‘b’ constants specific to each gas.
The equation can further be written as;
- Cube power of volume: V3−(b+RTP)V2+aPV−abP=0V3−(b+PRT)V2+PaV−Pab=0
- Reduced equation (Law of corresponding states) in terms of critical constants:
(π+3φ2)(3φ−1)=8τ:whereπ=PPc,φ=VVcandτ=TTc(π+φ23)(3φ−1)=8τ:whereπ=PcP,φ=VcVandτ=TcT
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सत्य सनातन? 4 years, 5 months ago
1Thank You