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State the condition under which bimolecular …

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State the condition under which bimolecular reaction is kinetically first order reaction...…..

Posted by Aashrity .... 5 years, 5 months ago

CBSE > Class 12 > Chemistry

2 answers

Khushi....? ??‍? 5 years, 5 months ago

A bimolecular reaction can be kinetically first order in behaviour provided one of the reactants is taken in such a large excess that its concentration may hardly change. Such a reactant will not contribute to the order. Thus, a bimolecular reaction will be of first order.

Vikas Shukla 5 years, 5 months ago

Generally molecularity and order of a reaction are same in elementary reaction. But in some cases order is found to be different. Such reactions are called Pseudo first order reactions. "This happens when one of the reactant is present in much excess quantity." ex - acidic hydrolysis of sucrose and Ester. (Molecularity is two but order is one.)

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