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Why this reaction CCl3-CH=CH2 + HCl …

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Why this reaction CCl3-CH=CH2 + HCl ~ CCI3-CH2-CH2Cl proceed as antimarkonikov rule as there is no peroxide there?

Posted by Tamanna Sharma 5 years, 10 months ago

CBSE > Class 12 > Chemistry

4 answers

Tamanna Sharma 5 years, 10 months ago

Why this secondary carbocation is unstable,explain. is it due to the chlorine

Mahi D 5 years, 10 months ago

Had the mechanism been markovnikov then a secondary carbocation would have developed on CH but here due to more electon withdrawing effect of three cl atoms the charge has become more +ve ... So to reduce this the carbocation will be developed on CH2 even in absence of peroxide.

Tamanna Sharma 5 years, 10 months ago

But all chlorines are not attached to CH2

Pritish Farswan 5 years, 10 months ago

Due to repulsion of three chlorine atoms Cl is attached to CH2 ( may be)

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