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Give a chemical test to distinguish …

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Give a chemical test to distinguish between phenol and benzoic acid
  • 4 answers

Shivani Thakur 5 years, 11 months ago

Phenol on mixing anhydrous fecl3...vl give a blue -back colour...bt not vth benzoic acid...

Atul Singh Rajput 5 years, 11 months ago

Coupling reaction Formation of orange dye in phenol

Yogita Ingle 5 years, 11 months ago

Phenol and benzoic acid can be distinguished by ferric chloride test.

Ferric chloride test:

Phenol reacts with neutral FeCl3 to form an iron-phenol complex giving violet colouration.

6C6H5OH + FeCl3 →[Fe(OC6H5)6]3- + 3H+ + 3 Cl-

But benzoic acid reacts with neutral FeCl3 to give a buff coloured ppt. of ferric benzoate.

3C6H5OH + FeCl3 → (C6H5COO)3Fe + 3 HCl

Sukirti Sharma 5 years, 11 months ago

ferric chloride test phenol give violet color ppt with FeCl3 whereas benzoic acid give buff color ppt with FeCl3
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