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How to name an organic compound

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How to name an organic compound
  • 3 answers

Nainil Jariwala 6 years ago

By nomenclature

Rishabh Singh 6 years ago

According to its no.of bonds and functional group and no. Of carbon on which the functional group has been used

Yogita Ingle 6 years ago

<pre>  </pre>

Prefix (alphabetically) root word (alk) primary suffix (ene, yne) secondary suffix (main functional group)

So IUPAC name of any organic compounds essentially consists of two or three parts.

(i)   Root word        (ii)   Suffix         (iii)  Prefix

(i) Root Words

The basic unit is a series of root words which indicate linear or continuous chains of carbon atoms. Chains containing one to four carbon atoms are known by special root words while chains from C5 onwards are known by Greek number roots.

<div>

Chain Length

Root word

Chain Length

Root word

C1

Meth-

C11

Undec-

C2

Eth-

C12

Dodec-

C2

Prop-

C13

Tridec-

C4

But-

C14

Tetradec-

C5

Pent-

C15

Pentadec-

C6

Hex-

C16

Hexadec-

C7

Hept-

C20

Eicos-

C8

Oct-

C30

Triacont-

C9

Non-

C40

Tetracont-

C10

Dec-

C50

Pentacont-

</div>

In general, the root word for any carbon chain in alk-.

(ii) Primary Suffix

Primary suffix are added to the root words to show saturation or unsaturation in a carbon chain.

<div>

Nature of carbon chain 

Primary suffix

Generic name

Saturated (C – C)

-ane

Alkane

Unsaturated (C = C)

with one double bond

-ene

Alkene

Unsaturated (C º C) with one triple bond

-yne

Alkyne

Unsaturated with two C = C bonds

-diene

Akladiene

Unsaturated with two C º C bonds 

-diyne

Alkadiyne

Unsaturated with three C = C bonds

-triene

Alkatriene

</div>

(iii) Secondary Suffixes

Suffixes added after the primary suffix to indicate the presence of a particular functional group in the carbon chain are known as secondary suffixes.

<div>

Functional Group

Secondary suffix

Alcohol (-OH)

-ol

Aldehyde (-CHO)

-al

Ketone (>CO)

-one-

Carboxylic acid (-COOH)

-oic acid

Sulphonic (-SO3H)

-sulphonic acid

Amine (-NH2)

-amine

Thioalcohol (-SH)

-thiol

Cyanide (-CN)

-nitrile

Ester (-COOR)

-oate

Amide (-CONH­2)

-amide

Acid halide (-COX)

-oyl halide

</div>

 

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