How to name an organic compound

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Posted by Niyathi Shine 6 years ago
- 3 answers
Rishabh Singh 6 years ago
Yogita Ingle 6 years ago
Prefix (alphabetically) root word (alk) primary suffix (ene, yne) secondary suffix (main functional group)
So IUPAC name of any organic compounds essentially consists of two or three parts.
(i) Root word (ii) Suffix (iii) Prefix
(i) Root Words
The basic unit is a series of root words which indicate linear or continuous chains of carbon atoms. Chains containing one to four carbon atoms are known by special root words while chains from C5 onwards are known by Greek number roots.
<div>|
Chain Length |
Root word |
Chain Length |
Root word |
|
C1 |
Meth- |
C11 |
Undec- |
|
C2 |
Eth- |
C12 |
Dodec- |
|
C2 |
Prop- |
C13 |
Tridec- |
|
C4 |
But- |
C14 |
Tetradec- |
|
C5 |
Pent- |
C15 |
Pentadec- |
|
C6 |
Hex- |
C16 |
Hexadec- |
|
C7 |
Hept- |
C20 |
Eicos- |
|
C8 |
Oct- |
C30 |
Triacont- |
|
C9 |
Non- |
C40 |
Tetracont- |
|
C10 |
Dec- |
C50 |
Pentacont- |
In general, the root word for any carbon chain in alk-.
(ii) Primary Suffix
Primary suffix are added to the root words to show saturation or unsaturation in a carbon chain.
<div>|
Nature of carbon chain |
Primary suffix |
Generic name |
|
Saturated (C – C) |
-ane |
Alkane |
|
Unsaturated (C = C) with one double bond |
-ene |
Alkene |
|
Unsaturated (C º C) with one triple bond |
-yne |
Alkyne |
|
Unsaturated with two C = C bonds |
-diene |
Akladiene |
|
Unsaturated with two C º C bonds |
-diyne |
Alkadiyne |
|
Unsaturated with three C = C bonds |
-triene |
Alkatriene |
(iii) Secondary Suffixes
Suffixes added after the primary suffix to indicate the presence of a particular functional group in the carbon chain are known as secondary suffixes.
<div>|
Functional Group |
Secondary suffix |
|
Alcohol (-OH) |
-ol |
|
Aldehyde (-CHO) |
-al |
|
Ketone (>CO) |
-one- |
|
Carboxylic acid (-COOH) |
-oic acid |
|
Sulphonic (-SO3H) |
-sulphonic acid |
|
Amine (-NH2) |
-amine |
|
Thioalcohol (-SH) |
-thiol |
|
Cyanide (-CN) |
-nitrile |
|
Ester (-COOR) |
-oate |
|
Amide (-CONH2) |
-amide |
|
Acid halide (-COX) |
-oyl halide |
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Nainil Jariwala 6 years ago
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