Graphite, named by Abraham Gottlob Werner in 1789, from the Greek γράφειν (graphein, "to draw/write", for its use in pencils) is one of the most common allotropes of carbon. Unlike diamond, graphite is an electrical conductor. Thus, it can be used in, for instance, electrical arc lamp electrodes. Likewise, under standard conditions, graphite is the most stable form of carbon. Therefore, it is used in thermochemistry as the standard state for defining the heat of formation of carbon compounds.
Graphite conducts electricity, due to delocalization of the pi bond electrons above and below the planes of the carbon atoms. These electrons are free to move, so are able to conduct electricity. However, the electricity is only conducted along the plane of the layers. In diamond, all four outer electrons of each carbon atom are 'localized' between the atoms in covalent bonding. The movement of electrons is restricted and diamond does not conduct an electric current. In graphite, each carbon atom uses only 3 of its 4 outer energy level electrons in covalently bonding to three other carbon atoms in a plane. Each carbon atom contributes one electron to a delocalized system of electrons that is also a part of the chemical bonding. The delocalized electrons are free to move throughout the plane. For this reason, graphite conducts electricity along the planes of carbon atoms, but does not conduct in a direction at right angles to the plane.
Graphite powder is used as a dry lubricant. Although it might be thought that this industrially important property is due entirely to the loose interlamellar coupling between sheets in the structure, in fact in a vacuum environment (such as in technologies for use in space), graphite was found to be a very poor lubricant. This fact led to the discovery that graphite's lubricity is due to adsorbed air and water between the layers, unlike other layered dry lubricants such as molybdenum disulfide. Recent studies suggest that an effect called superlubricity can also account for this effect.
When a large number of crystallographic defects(physical) bind these planes together, graphite loses its lubrication properties and becomes what is known as pyrolytic carbon, a useful material in blood-contacting implants such as prosthetic heart valves.
Graphite is the most stable allotrope of carbon. Contrary to popular belief, high-purity graphite does not readily burn, even at elevated temperatures.[3] For this reason, it is used in nuclear reactors and for high-temperature crucibles for melting metals.
Natural and crystalline graphites are not often used in pure form as structural materials due to their shear-planes, brittleness and inconsistent mechanical properties.
In its pure glassy (isotropic) synthetic forms, pyrolytic graphite and carbon fiber graphite are extremely strong, heat-resistant (to 3000 °C) materials, used in reentry shields for missile nosecones, solid rocket engines, high temperature reactors, brake shoes and electric motor brushes.
Intumescent or expandable graphites are used in fire seals, fitted around the perimeter of a fire door. During a fire the graphite intumesces (expands and chars) to resist fire penetration and prevent the spread of fumes.
Adi ??? 6 years, 2 months ago
1Thank You