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Why is bromination of phenol in …

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Why is bromination of phenol in water is trisubstituted but in CS2 is monosubstituted?

    • Posted by Pratistha Rawat 6 years ago

    CBSE > Class 12 > Chemistry
    • 1 answers

    Deeya Singh 6 years ago

    In water, phenol liberates H+ and forms phenoxide ion. This activates the Ortho and Para positions of phenol very much which leads to the formation of 2,4,6-Tribromophenol. Whereas nothing such happens when CS2 is used in bromination of phenol and only monosubstituted compound is formed.

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