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Out of chlorobenzene and benzyl chloride,which …

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Out of chlorobenzene and benzyl chloride,which one gets easily hydrolysed by aqueous NaOH and why?

Posted by Jk Verma 6 years, 3 months ago

CBSE > Class 12 > Chemistry

2 answers

Khuskaran Sidhu 6 years, 3 months ago

Benzyl chloride, because chlorobenzene is resonance stabilised

Řøhăň Řąjpůť ✌️✊ 6 years, 3 months ago

benzyl chloride will undergo hydrolysis in aq. NaoH becoz in benzyl chloride ch3-cl bond is polar due to inductive effect and hence more reactive... on the other hand in chlorobenzene the lone pair of cl atom is delocalised over the double bond ring of benzene which aad double bond character to the c-cl bond of chlorobenzene.this makes the bond stronger and can't be hydrolysed easily.

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