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Why alkyl halide immiscible with water?

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Why alkyl halide immiscible with water?

Posted by Alok Kumar Shah 5 years, 9 months ago

CBSE > Class 12 > Chemistry

1 answers

Sia ? 5 years, 9 months ago

To be miscible with water, the solute-water force of attraction must be stronger than the solute-solute and water-water forces of attraction. Alkyl halides are polar molecules and so held together by dipole-dipole interactions. Similarly, strong H-bonds exist between the water molecules. The new force of attraction between the alkyl halides and water molecules is weaker than the alkyl halide-alkyl halide and water-water forces of attraction. Hence, alkyl halides (though polar) are immiscible with water.

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