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Why SoCl2 is preferred for preparation …

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Why SoCl2 is preferred for preparation of Haloalkene

    • Posted by Meghan Bhangale 6 years, 7 months ago

    CBSE > Class 12 > Chemistry
    • 2 answers

    Sia ? 6 years, 7 months ago

    Thionyl chloride is preferred for preparing alkyl chlorides from alcohols because the by-products formed in the reaction are SO2 and HCl which are in gaseous form and escape into the atmosphere leaving behind pure alkyl chlorides.

    1Thank You

    Yogita Ingle 6 years, 7 months ago

    Alcohols on tratment with Sulphonyl Chloride[SOCl2](most preferrable) gives haloalkanes !

    CH3CH2OH + SOCl2 →  CH3CH2Cl + SO2 + HCl

    The Separation of the Haloalkane & Hydrogen chloride & Sulpher di-oxide are easier because SOCl2 & HCl are volaitle !!

    Thus this is the generally eaier way to prepare Haloalkanes

    1Thank You

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