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Why Raoult's law considerd as a …

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Why Raoult's law considerd as a special case of Henry's law?

    • Posted by Rahul Nehwal 6 years, 7 months ago

    CBSE > Class 12 > Chemistry
    • 1 answers

    Gaurav Seth 6 years, 7 months ago

    Raoult’s law as special case of Henry’s law

    • At a given temperature liquids vaporize. At equilibrium the pressure exertedby the vapour of the liquid over the liquidphase is referred to as vapour pressure.
    • According to Raoult’s law, vapour pressure of a volatile component in a given solution ca be defined by pi = pi 0 xi
    • In an answer of a gas in a fluid one of the segments is volatile to the point that it exists as a gas and solvency is given by Henry's law which expresses that p = KH x
    • Comparing both the equations we get that partial pressure of the volatile component or gas is directly proportional to its mole fraction in solution. Proportionality constant KH differs from p10
    • Therefore, Raoult's law turns into a unique instance of Henry’s law in which KH get to be equivalent to p10.

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