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Anti markoniv rule only hbr is …

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Anti markoniv rule only hbr is used why

    • Posted by Divya Rawat 6 years, 8 months ago

    CBSE > Class 12 > Chemistry
    • 2 answers

    Gaurav Seth 6 years, 8 months ago

    • In the presence of peroxides, the addition of HBr occurs by a free-radical mechanism and the orientation is anti-Markovnikov. This is true only for HBr.
    • Free radical addition of HF and HI has never been observed, even in the presence of peroxides, and of HCl only rarely.
    • In the rare cases where free-radical addition of HCl was noted, the orientation was still Markovnikov, because the more stable product was formed.
    • Free radical addition of HF, HI and HCl is energetically unfavourable.

    0Thank You

    Mohammad Owais 6 years, 8 months ago

    Bond dissosiation energy is lowest (One of the reasons)!!!

    1Thank You

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