How to convert galvanic cell into electrolytic cell?

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Dr. Kamlapati Bhatt 8 years, 4 months ago
Conversion of a galvanic cell into an electrolytic cell is practically possible by -
(i) connecting the cell to an external source of electricity , and
(ii) providing enough potential difference through this external source , such that , the applied emf exceeds the emf of the galvanic cell itself. [ for example > 1.1 V ,in case of simple Daniel cell ie.( Zn - Cu ) -cell. ]
Explanation :
Thus , In the beginning the external opposing potential is less than 1.1 V. In this case the normal cell reaction occurs in the galvanic cell and the current flows from copper electrode to zinc electrode. But when the opposing potential is increased slowly and gradually it is observed that normal reaction continues to occur till the opposing potential reaches to value of 1.1 V. At this stage the cell reaction stops .& the current continues to flow . Further increase in the opposing potential ( beyond 1.1 V ) again causes the chemical reaction to occur. But now the reaction occurs in opposite direction forcing Zn2+ ions to get reduced and Cu atoms to get oxidised.
Zn2+ (aq) + Cu (s) ----------> Zn (s) + Cu2+ (aq )
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