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Analysis shows that FrO has a …

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Analysis shows that FrO has a non stoichiometry composition with formula Fe0.95O. Give reason
  • 1 answers

Gaurav Seth 6 years, 11 months ago

The non-stoichiometry reflect the ease of oxidation of Fe2+ to Fe3+ effectively replacing a small portion of Fe2+ with two
thirds their number of Fe3+. Thus for every three "missing" Fe2+ ions, the crystal contains two Fe3+ ions to balance the
charge. i.e. 3Fe2+ = 2Fe3+ to maintain electrical neutrality.

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