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Haloalkanes react with KCN to form …

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Haloalkanes react with KCN to form alkyl cynide as the main product while AgCN form isocynide as the main product. Why?

Posted by Tina Bamel 7 years ago

CBSE > Class 12 > Chemistry

1 answers

Aniket Upadhyay 7 years ago

This is because KCN is ionic in nature so bond formation can take place through both C and N atom but since C-C bonds are stronger than C-N bons thus bond is formed through C atom hence cynide are firmed whereas AgCN is covalent in nature hence only N atom can take part in bond formation hence bond is forned by N atom .

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