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Why does carboxylic acid and aniline …

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Why does carboxylic acid and aniline does not undergo fridal carft reaction??

Posted by Aayush Kaushal 7 years, 2 months ago

CBSE > Class 12 > Chemistry

3 answers

G K 7 years, 2 months ago

Since friedel craft catalyst is a Lewis acid (e- deficient) the catalyst (anhyd AlCl3 ) reacts with e- rich COOH group of benzoic acid and gets bonded....... I think ? Friedel Craft r*n with Benzoic acid fails because the Benzene ring is deactivated......

G K 7 years, 2 months ago

Aniline does not undergo Friedel craft's reactions....... because the reagent AlCl3 (the Lewis acid which is used as a catalyst in friedel crafts reaction), being electron deficient acts as a Lewis base. and attacks on the lone pair of nitrogen present in aniline to form an insoluble complex which precipitates out and the reaction does not proceed........

Princesses Kaur 7 years, 2 months ago

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