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Why c-x bond in haloarene is …

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Why c-x bond in haloarene is smaller than c-x bond in haloalkane

    • Posted by Aditya Ranjan 7 years, 3 months ago

    CBSE > Class 12 > Chemistry
    • 1 answers

    Akshit Shinde 7 years, 3 months ago

    The lone pair of halogen atom delocalizes in the phenyl ring and develops a partial double bond character in C—X bond,making it more strong. But no such resonance possible in case of saturated halo-alkanes. So there is a difference in hybridisation of the C-X bond i.e.,in haloalkanes,the hybridisation is sp3 but in haloarenes it is sp2 . So halogen atom is hold more tightly in halo-arenes.So c-x of haloarene is smaller than c-x of haloalkane.

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