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Haloalkanes react with kCN to form …

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Haloalkanes react with kCN to form alkyl cynides while AgCN forms isocynides as the chief product why

Posted by Yashi Jain 7 years, 5 months ago

CBSE > Class 12 > Chemistry

2 answers

Shubham Sharma 7 years, 5 months ago

KCN being ionic in nature have unequal distribution of electron b/w K and C .as a result C have extra lone pair of electron which it donate to alkyl part forming alkyl cyanide . whereas AgCN is covalent in nature due to which C does not have lone pair of electron . as a result N having a lone pair of electron donate it to alkyl part forming isocyanides

Pooja Sharma 7 years, 5 months ago

AgCN is covalent in nature

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