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Dr. Kamlapati Bhatt 8 years, 4 months ago
According to the formula oxidation state of N in HNO3 is +5 ,as calculated below.
Let the oxidation state of N be x , then applying the rules to calculate O.N. , we get
+1 +(x) + (- 2 X 3 ) = 0
{tex}\therefore{/tex} x = ( +6 - 1 )
= +5
We know that , N is restricted to a maximum covalency of 4 , since only four (1s and 3p ) orbitals are available for bonding , and also due to the absence of a d-orbital in the atom. However , there are cases where oxidation state of N in compounds like viz . N2 O5 , HNO3 is +5 . This is due to resonating structures of these compounds . Their resonating structures well support and justify the oxidation number of N as +5 in the compound as follows -
Resonating structure of HNO3 results into formation of a coordinate bond , where N donates both the electrons to oxygen atom.
and the double bond is formed with one of the oxygen atoms giving a charge as +2 to N
A single bond with the other oxygen atom gaining a negative charge over it gives a charge of +2 to N
& OH- group gives a charge to N as = +1
Adding up all the charges provided to N in HNO3 ,
Oxidation No. of N in HNO3 = 2+2+1 = 5
similarly the oxidation state of N in N2 O5 can also be made out through its structure as given above.
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