No products in the cart.

In page number 167 of 1st …

CBSE, JEE, NEET, CUET

CBSE, JEE, NEET, CUET

Question Bank, Mock Tests, Exam Papers

NCERT Solutions, Sample Papers, Notes, Videos

In page number 167 of 1st part of Chemistry book it is given in 20th line that nitrogen exist +1 to +4 oxidation state but in the example given below the line, nitrogen is exhibiting +5 oxidation state in HNO3 molecule

  • 1 answers

Dr. Kamlapati Bhatt 8 years, 4 months ago

According to the formula oxidation state of  N in  HNO3 is  +5 ,as calculated below.

Let  the oxidation state of N be  x , then applying the rules to calculate O.N. , we get

+1  +(x)   + (- 2 X 3 )  =  0

{tex}\therefore{/tex}   x   =  (  +6  - 1 )

=  +5 

We know that , N is restricted to a maximum covalency of  4 , since only  four (1s  and 3p  )  orbitals are available for bonding , and also due to the absence of a d-orbital in the atom. However , there are cases where   oxidation state of N in compounds like  viz .  N2 O,  HNO3    is  +5 . This is due to resonating structures  of  these compounds .  Their resonating structures well support and justify the oxidation number of N as  +5  in the compound  as follows - 

 

Resonating structure of HNO3 results into formation of a coordinate bond , where N donates both the electrons to oxygen atom. 

and the double bond is formed with one of the oxygen atoms  giving  a charge as  +2 to N

A single bond with the other oxygen atom gaining a negative charge over it  gives  a charge of  +2  to  N

&  OH- group  gives  a charge to N as  =  +1

Adding up all the charges provided to N in HNO3  ,

Oxidation  No.  of  N  in  HNO3   =   2+2+1  =  5 

similarly the oxidation state of N  in  N2 O5 can  also be  made out through its structure as given above. 

https://examin8.com Test

Related Questions

Can we keep caso4 using vessel justify your answer
  • 1 answers
Arrhenius concept
  • 0 answers

myCBSEguide App

myCBSEguide

Trusted by 1 Crore+ Students

Test Generator

Test Generator

Create papers online. It's FREE.

CUET Mock Tests

CUET Mock Tests

75,000+ questions to practice only on myCBSEguide app

Download myCBSEguide App