In group 15 trihalides,bond angle increases …
CBSE, JEE, NEET, CUET
Question Bank, Mock Tests, Exam Papers
NCERT Solutions, Sample Papers, Notes, Videos
Posted by Tamanna Bhanwala 8 years, 2 months ago
- 1 answers
Related Questions
Posted by Karan Kumar Mohanta 9 months, 3 weeks ago
- 1 answers
Posted by Roshni Gupta 10 months, 2 weeks ago
- 0 answers
Posted by Neha 107 10 months, 1 week ago
- 0 answers
Posted by Mahi Sharma 10 months, 3 weeks ago
- 0 answers
Posted by Kashish Baisla 2 months, 1 week ago
- 1 answers
Posted by Shivam Modanwal 10 months, 1 week ago
- 0 answers
Posted by Priya Dharshini B 9 months, 4 weeks ago
- 4 answers
Posted by Cinvi Patel 10 months, 1 week ago
- 0 answers
myCBSEguide
Trusted by 1 Crore+ Students
Test Generator
Create papers online. It's FREE.
CUET Mock Tests
75,000+ questions to practice only on myCBSEguide app
Shweta Gulati 8 years, 2 months ago
All these hydrides are covalent in nature and have pyramidal structure. These involve sp3 hybridization of the central atom and one of the tetrahedral positions is occupied by a lone pair.Due to the presence of lone pair, the bond angle in NH3 is less than the normal tetrahedral angle. It has been found to be 107 degrees. Down the group the bond angle decreases as:
In all these hydrides, four electron pairs, three bond pairs and one lone pair surround the central atom. Now, as we move down the group from N to Bi, the size of the atom goes on increasing and its electro negativity decreases. Consequently, the position of bond pair shifts more and more away from the central atom in moving from NH3 to BiH3. For e.g., the bond pair in NH3 is close to N in N-H bond than the bond pair in P-H bond in PH3. As a result, the force of repulsion between the bonded pair of electrons in NH3 is more than in PH3. In general, the force of repulsion between bonded pairs of electrons decreases as we move from NH3 to BiH3 and therefore, the bond angle also decreases in the same order.
0Thank You