equation of when we change ethanoic …

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Dr. Kamlapati Bhatt 8 years, 4 months ago
Following steps / reactions would convert ethanoic acid to methanoic acid .
1.Reaction of ethanoic acid with NH3 to form ethanamide , C H3 CO NH2
CH3 COOH ---------------NH3 + H2 O----------> CH3 COONH4 ---- {tex}\Delta{/tex}----------> CH3 CO NH2
or, CH3 COOH + NH3 ----------Al2O3 /{tex}\Delta{/tex}-----> CH3 CO NH2
2. Treat ethanamide with ( alcoholic KOH + Br2 ) to get methanamine CH3 NH2 .....( ie.Hoffmann's Bromamide reaction )
CH3 CO NH2 ------ KOH (alcoholic) + Br2 -------------> CH3 NH2 + K2 CO3 + H2 O
3. Reduction of CH3 NH2 with HNO2 to get methanol .
CH3 NH2 -------------[H] / HNO2-----------> CH3OH + N2 + H2 O
4. Oxidation of methanol with ( K2 Cr2 O7 + dil. H2 S O4) yields methanoic acid.
CH3 OH -------[2 O ] / ( K 2 Cr 2 O7 + dil. H 2SO4 ) -------- HCOOH
1Thank You