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equation of when we change ethanoic …

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equation of when we change ethanoic acid into methanoic
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Dr. Kamlapati Bhatt 8 years, 4 months ago

Following steps / reactions would convert ethanoic acid to  methanoic acid .

1.Reaction  of ethanoic acid with  NH3  to form  ethanamide ,   C H3 CO  NH2

CH3 COOH ---------------NH3 +  HO----------> CH3 COONH4 ---- {tex}\Delta{/tex}---------->  CH3 CO NH2   

or, CHCOOH    +    NH3 ----------Al2O3 /{tex}\Delta{/tex}-----> CH3 CO NH2 

2.  Treat  ethanamide  with ( alcoholic KOH  +   Br2 ) to get methanamine CH3 NH2  .....(  ie.Hoffmann's Bromamide reaction )

CH3 CO NH2  ------  KOH (alcoholic)  +  Br2   ------------->   CH3 NH2     +  K2 CO3   +   H2 O 

3.  Reduction   of  CH3 NH2   with  HNO2  to get methanol  .  

CH3 NH2 -------------[H] /  HNO2----------->   CH3OH   +  N2    +    HO

4. Oxidation of methanol with ( KCr2 O7 +  dil.  H2 S O4) yields  methanoic acid.

CH3 OH  -------[2 O ] /  ( K 2 Cr 2 O7  +  dil. H 2SO4 ) -------- HCOOH     

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