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18g of glucose is dissolved in …

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18g of glucose is dissolved in 1kg of water in a sauce pan .at what temperature wii this solution boil
  • 1 answers

Dr. Kamlapati Bhatt 8 years, 4 months ago

Calculations :   

Moles of glucose  ,  C6 H12 O6 

=   Mass of glucose  /   malar mass of glucose

=    {tex}\frac{18}{180}{/tex} mol

=  0.1 mol

Number of Kg of solvent  

=  1 kg ........(given)

{tex}\therefore{/tex}molality (m)  of glucose solution 

=   0.1 mol kg-1 

For water , change in boiling point is given by the expression ,

{tex}\Delta T{/tex}b    =    Kb x m

where  ,   Kb is Molal boiling point elevation constant is known as  

=  0.52  K  kg mol-1   

and  m  represents molality

=  0.1 mol kg-1   ......calculated as above 

So  , substituting the values in above expression we get ,

{tex}\Delta Tb = 0.52kg mol^-1 X 0.1 mol kg^-1{/tex}

=  0.052 K

Since water boils at 373.15 K at 1.013 bar pressure , therefore the boiling point of solution will be 

=  ( 373.15  +   0.052 ) K

=373.202 K 

 

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