HOW CAN WE DETERMINE THE REACTION …

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Posted by Abhishek Shikhare 8 years, 11 months ago
- 2 answers
Naveen Sharma 8 years, 11 months ago
Ans. The order of a chemical reaction is defined as the sum of the powers of the concentration of the reactants in the rate equation of that particular chemical reaction. A reaction can also have a reaction order with respect to a reactant if the rate is not simply proportional to some power of the concentration of that reactant.
Consider a general reaction:
The rate expression for this reaction is (say) :
Here, x and y indicate how sensitive the rate is to the change in concentration of A and B.
Hence, the order of this reaction is (x + y).
Note that the x and y may not respectively correspond to the stoichiometric coefficients of A and B.
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Yakshith K 8 years, 11 months ago
Along with the below answer you can sometimes just easily determine the order of reaction just by the unit/dimension of the rate of reaction.
ZERO ORDER:
<font size="+2">rate = k[A]0</font>
<font size="+2"> M/t = k</font>
<font size="+2">K units: M/s, M/min, M/hr, etc.</font>
FIRST ORDER:
<font size="+2">rate =K[A]</font>
<font size="+2"> M/t =K M</font>
<font size="+2"> Kunits: s-1, min-1, hr-1, etc.</font>
SECOND ORDER:
<font size="+2">rate =K[A]2 rate =K[A][B]</font>
<font size="+2"> M/t =KM2</font>
<font size="+2">Kunits: M-1s-1, M-1min-1, M-1hr-1, etc.</font>
THIRD ORDER:
<font size="+2">rate =K[A]3 rate =K[A]2[B] rate =K[A][B][C]</font>
<font size="+2"> M/t =K M3</font>
<font size="+2">Kunits: M-2s-1, M-2min-1, M-2hr-1, etc.</font>
N ORDER:
<font size="+2">rate =K[A]n</font>
<font size="+2"> M/t =K Mn</font>
<font size="+2">Kunits: M-(n-1)s-1</font>
1Thank You