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HOW CAN WE DETERMINE THE REACTION …

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HOW CAN WE DETERMINE THE REACTION IS FIRST SECOND OR ZERO ORDER OF REACTION

  • 2 answers

Yakshith K 8 years, 11 months ago

Along with the below answer you can sometimes just easily determine the order of reaction just by the unit/dimension of the rate of reaction. 

ZERO ORDER:
<font size="+2">rate = k[A]0</font> 
<font size="+2"> M/t = k</font> 

<font size="+2">K units:  M/s, M/min, M/hr, etc.</font>

FIRST ORDER: 
<font size="+2">rate =K[A]</font> 
<font size="+2"> M/t =K M</font> 
<font size="+2">  Kunits: s-1, min-1, hr-1, etc.</font>

SECOND ORDER:
<font size="+2">rate =K[A]2      rate =K[A][B]</font> 
<font size="+2"> M/t =KM2</font> 

<font size="+2">Kunits: M-1s-1, M-1min-1, M-1hr-1, etc.</font>

THIRD ORDER: 
<font size="+2">rate =K[A]3      rate =K[A]2[B]     rate =K[A][B][C]</font> 
<font size="+2"> M/t =K M3</font> 

<font size="+2">Kunits: M-2s-1, M-2min-1, M-2hr-1, etc.</font>

N ORDER: 
<font size="+2">rate =K[A]n</font> 
<font size="+2"> M/t =K Mn</font> 

<font size="+2">Kunits: M-(n-1)s-1</font>

Naveen Sharma 8 years, 11 months ago

Ans. The order of a chemical reaction is defined as the sum of the powers of the concentration of the reactants in the rate equation of that particular chemical reaction. A reaction can also have a reaction order with respect to a reactant if the rate is not simply proportional to some power of the concentration of that reactant.

Consider a general reaction:

aA + bB cC + dD 

The rate expression for this reaction is (say) :  -ra = kAxBy

Here,  x and y indicate how sensitive the rate is to the change in concentration of A and B.

Hence, the order of this reaction is (x + y).

Note that the x and y may not respectively correspond to the stoichiometric coefficients of A and B.

 

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