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E°(A2+/A) = -2.37V and E°(B2+/B) = …

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E°(A2+/A) = -2.37V and E°(B2+/B) = -0.14V. Which of these is better for coating the surface of iron [E°(Fe2+/Fe) = -0.44V] to prevent corrosion and why?
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