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Meghna Thapar 5 years, 4 months ago
p H = 10
Using formula [H+] = 10-pH
So [H+] = 10-10 M
Electrode reaction will be
H+ + e- → ½ H2
Use the formula
Value of E0 = 0
Ecell = E0 - 0.0591 log[H2]
1 [H+]
Ecell = - 0.0591 log( 1/10-10)
1
Ecell = - 0.0591 ( 10) = -0.591 V
Posted by Nisha Yadav 5 years, 4 months ago
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Yogita Ingle 5 years, 4 months ago
Dow’s process is a method to prepare phenol. The reactant chlorobenzene is heated with aqueous sodium hydroxide at temperature 623K and 300atm to get sodium phenoxide ion. Then in the next step sodium phenoxide ion is treated with Dilute HCl which gives the final product as phenol.
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Kolbe reaction, also known as Kolbe Schmitt Reaction is a type of addition reaction named after Hermann Kolbe and Rudolf Schmitt. When phenol is treated with sodium hydroxide, phenoxide ion is generated. The phenoxide ion generated is more reactive than phenol towards electrophilic aromatic substitution reaction. Hence, it undergoes electrophilic substitution reaction with carbon dioxide, which is a weak electrophile. Ortho-hydroxybenzoic acid (salicylic acid) is formed as the primary product. This reaction is popularly known as Kolbe’s reaction.
An example of the Kolbe reaction (Kolbe Schmitt Reaction) is given below:

Kolbe’s Reaction – Treating phenol with sodium hydroxide generates phenoxide ion
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Bond angles in ammonia and ammonium ion.
The bond angles in ammonium ion, NH4+ are the theoretical tetrahedral bond angles of approximately 109.5 degrees. The ammonium ion is completely symmetrical.
The bond angles in the asymmetrical ammonia molecule are less than 109.5 degrees, they are about 107 degrees. This is due to the repulsion of the bonding pairs and the lone pair.
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Yogita Ingle 5 years, 4 months ago
Bond angles in ammonia and ammonium ion.
The bond angles in ammonium ion, NH4+ are the theoretical tetrahedral bond angles of approximately 109.5 degrees. The ammonium ion is completely symmetrical.
The bond angles in the asymmetrical ammonia molecule are less than 109.5 degrees, they are about 107 degrees. This is due to the repulsion of the bonding pairs and the lone pair.
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Primitive Unit Cells
If the constituent particles of a crystal lattice are present only on the corner positions of a unit cell, it is known as primitive unit cell.
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Sushmita Yadav 5 years, 4 months ago
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