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Posted by Pushpraj Singh Rajput 5 years, 3 months ago
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Gaurav Seth 5 years, 3 months ago
- When amide is treated with Br2 in aqueous or ethanolic solution of NaOH, degradation of amide results in formation of primary amine.
- Primary amine formed contains one carbon less than the number of carbon atoms in amide.
O
∣∣
R−C−NH2+Br2+4NaOH⟶R−NH2+Na2CO3+2NaBr+2H2O
Mechanism:
- Base attacks amide deprotonating it and generating anion.
- Anion reacts with Br2 forming bromoamide.
- Deprotonation of bromoamide occurs forming bromoamide anion which undergoes rearrangement forming isocyanate.
- Isocyanate forms carbamic acid by addition of H2O molecules.
- Decarboxylation of carbamic acid occurs forming primary amine.
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Posted by Tanya Gupta 5 years, 3 months ago
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Gaurav Seth 5 years, 3 months ago
Kohlrausch law of independent migration of ions: The law states that limiting molar conductivity of an electrolyte can be represented as the sum of the individual contributions of the anion and cation of the electrolyte.

Posted by Iqbal Singh 5 years, 3 months ago
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Yogita Ingle 5 years, 3 months ago
Steric hindrance is when the large size of groups within a molecule prevents chemical reactions which can take place in related molecules with smaller groups. Steric hindrance is also a reason for protection of some groups from unwanted chemical modifications.
Vikas Shukla 5 years, 3 months ago
Posted by Iqbal Singh 5 years, 3 months ago
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Iqbal Singh 5 years, 3 months ago
Iqbal Singh 5 years, 3 months ago
Vikas Shukla 5 years, 3 months ago
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Posted by Sushmita Kaushik 5 years, 3 months ago
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Yogita Ingle 5 years, 3 months ago
Atomic radius decreases across a period because valence electrons are being added to the same energy level at the same time the nucleus is increasing in protons. The increase in nuclear charge attracts the electrons more strongly, pulling them closer to the nucleus.
Explanation:
The following diagram shows the periodic trends of atomic radius of the representative elements (main group elements) for the first six periods.

Posted by Shubham Ranjan 5 years, 3 months ago
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Gaurav Seth 5 years, 3 months ago
The dipole moment of chlorobenzene is less than cyclo hexyl chloride as in chloro benzene C-Cl bond is sp2 hybridised where as in cyclohexyl chloride the C_cl bond is Sp3 Hybridised . as sp2 has more s character and more electronegative than sp3. Chlorobenzene is less polar than cyclohexyl chloride.
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Souparnika Gopakumar 5 years, 3 months ago
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Posted by Aryan Singh 5 years, 3 months ago
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Yogita Ingle 5 years, 3 months ago
Carboxylic acid are more acidic than phenols because the negative charge in carboxylate anion is more spread out as compared to the phenoxide ion as there are two electronegative O-atoms in carboxylate anion in comparison to one in phenoxide ion. ... So Formic acid is more acidic than acetic acid
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Deepak . 5 years, 3 months ago
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Iqbal Singh 5 years, 3 months ago
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Atul Sharma 5 years, 3 months ago
Iqbal Singh 5 years, 3 months ago
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Iqbal Singh 5 years, 3 months ago
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Iqbal Singh 5 years, 3 months ago
Iqbal Singh 5 years, 3 months ago
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Posted by Iqbal Singh 5 years, 3 months ago
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Iqbal Singh 5 years, 3 months ago
Posted by O The 5 years, 3 months ago
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Yogita Ingle 5 years, 3 months ago
Ferromagnetism – The substances which are strongly attracted by the magnetic field & show permanent magnetism even when the magnetic field is removed are known as ferromagnetic substances.When there is spontaneous alignment of magnetic moments of domain in the same direction,ferromagnetism happens
Posted by Rainsy Dhakad 5 years, 3 months ago
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Nidhi Sahu 5 years, 3 months ago
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Akanksha Kumari 5 years, 3 months ago
1Thank You