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Yogita Ingle 4 years, 2 months ago
In the presence of organic peroxides, bromides will take part in radical based reactions. Fission of the peroxide O-O linkage will induce a Br radical which behaves differently to Bromide, by adding to the less substituted side of the alkene (anti - markovnikov). HI and HCl do not do this for energetic reasons.
The addition of Cl and I radicals to the alkene in an anti-markovnikov fashion is an endothermic reaction and therefore unfavourable. Without the presence of peroxide, all hydrogen halides will add according to the markovnikov rule.
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Gaurav Seth 4 years, 2 months ago
A n s w e r is :
4.0 x 1015
Explanation :
For a cell reaction in equilibrium at 298 K,
where KC = equilibrium constant, n = number of electrons involved in the electrochemical cell reaction.
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Yogita Ingle 4 years, 2 months ago
When two phases meet, the boundary between them is known as an interface.
We have the following interfaces :
1) Solid - Solid interface
2) solid - liquid interface
3) liquid - liquid interface
4) Gas - liquid interface
5) Gas - Solid interface.
We do not have a gas - gas interface because gases diffuse rapidly and quickly therefore we cannot tell their interface.
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Gaurav Seth 4 years, 2 months ago
- When amide is treated with Br2 in aqueous or ethanolic solution of NaOH, degradation of amide results in formation of primary amine.
- Primary amine formed contains one carbon less than the number of carbon atoms in amide.
O
∣∣
R−C−NH2+Br2+4NaOH⟶R−NH2+Na2CO3+2NaBr+2H2O
Mechanism:
- Base attacks amide deprotonating it and generating anion.
- Anion reacts with Br2 forming bromoamide.
- Deprotonation of bromoamide occurs forming bromoamide anion which undergoes rearrangement forming isocyanate.
- Isocyanate forms carbamic acid by addition of H2O molecules.
- Decarboxylation of carbamic acid occurs forming primary amine.
How satisfied are you with the an
Posted by Tanya Gupta 4 years, 2 months ago
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Gaurav Seth 4 years, 2 months ago
Kohlrausch law of independent migration of ions: The law states that limiting molar conductivity of an electrolyte can be represented as the sum of the individual contributions of the anion and cation of the electrolyte.
Posted by Iqbal Singh 4 years, 2 months ago
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Yogita Ingle 4 years, 2 months ago
Steric hindrance is when the large size of groups within a molecule prevents chemical reactions which can take place in related molecules with smaller groups. Steric hindrance is also a reason for protection of some groups from unwanted chemical modifications.
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Deepak Soni 4 years, 1 month ago
2Thank You