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Dr. Kamlapati Bhatt 8 years, 4 months ago
The commonly termed ether , diethyl ether ( CH3 CH2 O CH2 CH3 ) when perfectly free from water is called dry ether .
Ether absorbs H2 O from atmosphere. Many organic reactions are sensitive to H2 O , so it must be removed from ether before it being used in the reaction .The best way to remove water from ether is to reflux it over sodium . Sodium will dry out water . However, other a nonreactive water absorber ( or dehydrating agent ) such as MgSO4 have also been used to remove even traces of water from ether.
Posted by Sachin Singh 8 years, 4 months ago
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Dr. Kamlapati Bhatt 8 years, 4 months ago
, Faraday's laws of electrolysis is a part of our syllabus and has been dealt with in the Chapter " Electrochemistry "as per NCERT class 12 book.
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Minakshi Kapoor 8 years, 4 months ago
Hydrogen and bromine serves as the system’s electrolyte. During the charge cycle, as power flows into the stack, H2 is generated and stored in a separate tank. An additional product of the chemical reaction is HBr3, which is also an electrolyte and is mixed in the same tank as the HBr. During the discharge cycle H2 is consumed and energy is generated. The H2 is combined again with the HBr3 and the system returns to its initial stage with a full tank of HBr. The electrolyte suffers no degradation during the process and the system is self contained with no emissions.
Posted by Kundan Kumar 8 years, 4 months ago
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Dr Pathikrt Banerjee 8 years, 4 months ago
Practice in writing the same reaction more than once and you will find yourself in a much better position. Best of Luck.
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Dr. Kamlapati Bhatt 8 years, 4 months ago
The order of reaction is = 1
Explanation :
The order of reaction can be calculated through following steps -
Step 1 / Calculate k for the reaction using expression ,
k = 0.693 / t1/2
= o.693 / 2 ......since t1/2 is given as = 2 hours
= 0.3465 hrs-1
Apply first order rate expression ,
k = {tex}\frac{2.303}{t}{/tex} log{tex}\frac{Ro}{R}{/tex} , at time t = 4 hours ,
= {tex}\frac{2.303}{4}log{/tex} {tex}\frac{100}{(100-75)}{/tex}
= 0.575575 log 4
= 0.57557 x 0.60206
= 0.3465 hr-1
Thus , same value of rate constant k is using first order rate equation , confirms the order of reaction = 1
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Dr. Kamlapati Bhatt 8 years, 4 months ago
CFT (Crystal Field Theory ) is a model which describes the breaking of degeneracies in electron orbital states , usually d and f -orbitals , due to static electrical field produced by ligands surrounding the central metal ion in a coordination compound , thus stabilising the complex.
Posted by Kanak Bali 8 years, 4 months ago
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Dr. Kamlapati Bhatt 8 years, 4 months ago
Surfactant in solution are often associated colloids , that is they tend to form aggregates of colloidal dimensions which exist in equilibrium with molecules or ions from which they are formed . Such aggregated particles are termed as " micelles ". These are , therefore, also known as associated colloids.
Micelles are formed when a variety of molecules including soaps and detergents are added to water . The molecule may be a fatty acid , a salt of fatty acid ( soaps ) ,phospholipids or other similar molecules . the molecule must have strongly polar ' head ' and a non polar chain of hydrocarbons ' tail.When this type of molecule is added to water the nonpolar tails of the molecule clump in to the centre of a ball like structure called micelle , because they are hydrophopic ( or water hating ) The polar head of the molecule presents itself for interaction with water molecules at the ouside of micelles.
Posted by Manisha Kumari 8 years, 4 months ago
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Dr. Kamlapati Bhatt 8 years, 4 months ago
Mischmetal is an alloy of rare earth elements .There is no exact formulation of mischmetal . However , a typical composition of mischmetal is ; Cerium - 50% ,Lanthanum -- 25 % , smaller amounts of praseodymium , neodymeum and a few other trace rare earths making up the balance .
Posted by Abhishek Kumar 8 years, 4 months ago
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Govind Singh 7 years, 11 months ago
{tex}CHF3 \to CF - \; + \;H + {/tex}
{tex}CHCl3 \to CCl3 - \; + H + {/tex}
CF3- is not stable by resonance due to the absence of d-orbitals on F but CCl3- is stable by resonance due to the presence of d-orbitals on Cl. So, CHCl3 is more acidic than CHF3.
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Amzker Pro Hacker 6 years, 7 months ago
1) React Cl-Benzene To NAOH & then with HCL ===> Phenol
2) Reimertiman
Phenol + Ch3cl|KOH 60-70° ==>salicyaldehyde
OR
i) Phenol +K2Cr2O7(in H2So4) =>Benzaldehyde
ii) benzaldehyde ,Chlorination
Then Naoh/HCL , =>salicyaldehyde
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