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Gurvinder Kaur 7 years, 11 months ago
Tollens' reagent is freshly prepared ammonical silver nitrate solution. Aldehydes react with tollens' reagent and a bright silver mirror is formed due to the formation of silver metal. The aldehydes will get oxidised to carboxylate anion. This reaction occurs in alkaline medium. Ketones will not give silver mirror test. The reaction is :
RCHO + 2[Ag (NH3)2]+ + 3OH- → RCOO- + 2Ag + 2H2O + 4NH3
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Gurvinder Kaur 7 years, 11 months ago
The phenomenon of attracting and retaining the molecules of a substance on the surface of a liquid or a solid resulting into a higher concentration of the molecules on the surface is called adsorption. The substance thus adsorbed on the surface is called the adsorbate and the substance on which it is absorbed is known as adsorbent. The reverse process i.e. removal of the adsorbed substance from the surface is called desorption. The adsorption of gases on the surface of metals is called occlusion.
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Gurvinder Kaur 7 years, 11 months ago
J = sigma E
We know, J = I/A
I = n e A (vd) [in terms of drift velocity of electrons]
Therefore, J = neA(vd)/A = ne (vd)
Now, vd = -e E (tau) /m [ drift velocity of electrons in terms of relaxation time tau]
Therefore, J = n (e square) E (tau)/m
And we know, rho = m / n (e square) (tau)
And 1/rho = sigma = n (e square) (tau) / m
Therefore, J = sigma E
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Gurvinder Kaur 7 years, 11 months ago
Rate law is the expression in which reaction rate is given in terms of molar concentration of ractants with each term raised to some power, which may or may not be same as stoichiometric coefficient of the reacting species in a balanced chemical equation.
For example: 2NO + O2 {tex}\to{/tex} 2NO2
hence the rate law = k [NO]2 [O2]
here k is rate constant.

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