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Solvate or hydrate isomerism are the isomers which have the same composition but the solvate isomers differ by whether or not a solvent molecule is directly bonded to the metal ion or is merely present on free solvent molecules in the crystal.
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Cell is the smallest structural and functional unit of an organism, which is typically microscopic and consists of cytoplasm and a nucleus enclosed in a membrane.
200 different types of cells are there.
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Micro-chemical methods are available for several of the practical experiments. Wherever possible, such techniques should be used.
- Surface Chemistry
- Preparation of one lyophilic and one lyophobic sol Lyophilic sol - starch, egg albumin and gum Lyophobic sol - aluminium hydroxide, ferric hydroxide, arsenous sulphide.
- Dialysis of sol-prepared in (a) above.
- Study of the role of emulsifying agents in stabilizing the emulsion of different oils.
- Chemical Kinetics
- Effect of concentration and temperature on the rate of reaction between Sodium Thiosulphate and Hydrochloric acid.
- Study of reaction rates of any one of the following:
- Reaction of Iodide ion with Hydrogen Peroxide at room temperature using different concentration of Iodide ions.
- Reaction between Potassium Iodate, (KIO3) and Sodium Sulphite: (Na2SO3) using starch solution as indicator (clock reaction).
- Thermochemistry
Any one of the following experiments- Enthalpy of dissolution of Copper Sulphate or Potassium Nitrate.
- Enthalpy of neutralization of strong acid (HCI) and strong base (NaOH).
- Determination of enthalpy change during interaction (Hydrogen bond formation) between Acetone and Chloroform.
- D. Electrochemistry
Variation of cell potential in Zn/Zn2+|| Cu2+/Cu with change in concentration of electrolytes (CuSO4 or ZnSO4) at room temperature. - Chromatography
- Separation of pigments from extracts of leaves and flowers by paper chromatography and determination of Rfvalues.
- Separation of constituents present in an inorganic mixture containing two cations only (constituents having large difference in Rf values to be provided).
- Preparation of Inorganic Compounds
- Preparation of double salt of Ferrous Ammonium Sulphate or Potash Alum.
- Preparation of Potassium Ferric Oxalate.
- Preparation of Organic Compounds Preparation of any one of the following compounds
- Acetanilide
- Di -benzal Acetone
- p-Nitroacetanilide
- Aniline yellow or 2 - Naphthol Aniline dye.
- Tests for the functional groups present in organic compounds:
Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (Primary) groups. - Characteristic tests of carbohydrates, fats and proteins in pure samples and their detection in given food stuffs.
- Determination of concentration/ molarity of KMnO4 solution by titrating it against a standard solution of:
- Oxalic acid,
- Ferrous Ammonium Sulphate (Students will be required to prepare standard solutions by weighing themselves).
- Qualitative analysis
Determination of one cation and one anion in a given salt.
Cation - Pb2+, Cu2+, Al3+, Fe3+, Mn2+, Zn2+, Cu2+, Co2+, Ni2+, Ca2+, Sr2+, Ba2+ , Mg2+,[NH4]+
Anions – [CO3]2- , S2- , [SO3]2- , [SO4]2- , [NO2]- , Cl- ,Br- , I- , [PO4]3- , [C2O4]2- , CH3COO- (Note: Insoluble salts excluded)
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