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Yogita Ingle 6 years, 3 months ago
The Kolbe reaction can be classified as a carboxylation chemical reaction. The reaction occurs when sodium phenoxide is allowed to absorb carbon dioxide and the resulting product is heated at a temperature of a 125-degree celsius and a pressure of over a hundred atmospheres. An unstable intermediate is now formed.
This unstable intermediate goes through a proton shift, leading to the formation of sodium salicylate. Now, this mixture is treated with sulfuric acid. The acidification of the mixture yields the salicylic acid. The illustration for the Kolbe reaction mechanism is given below:

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Benzyl chloride undergoes SN1 reaction faster than cyclhexyl chloride because in case of benzyl chloride, the carbocation formed after the loss of CL- is stablised by resonance, whereas , no such stabilization is possible in the carbonation obtained from cyclohexyl methyl chloride.
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The attractive intermolecular forces are called vander Waals’ force. in honor of Dutch scientist Johannes van der Waals (1837-1923) as he explained the deviation of real gases from the ideal behaviour through these forces.
Van-der Waals’ s forces vary considerably in magnitude and include , dispersion forces or London forces, dipole-dipole forces, and dipole-induced dipole forces.
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Yogita Ingle 6 years, 3 months ago
Rate law
- The representation of rate of reaction in terms of molar concentration of the reactants participating in a reaction raised to some power is called rate law.
- It is also called rate expression or rate equation.
- Consider a reaction:
2NO (g) + O2 (g) --> 2NO2
Rate ∝ [NO]2
Rate ∝ [O2]
Combining these two rates we derive
Rate ∝ [NO]2 [O2]
Rate =k [NO]2 [O2]
- Where k is the proportionality constant with a definite value at a specific temperature for a specific reaction and is called Rate Constant.
- Rate law expression = -d[R]/ dt = k [NO]2 [O2]
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Yogita Ingle 6 years, 3 months ago
A non-volatile solute does produce vapour at the boiling point of the solution. They have lower vapour pressure and higher boiling point.
<div>Example: Sugar.
A volatile solute produces vapour at the boiling point of the solution. At the same temperature, they have higher vapour pressure than non-volatile solutes.
Examples: Alcohol, ether, mercury, and gasoline.
</div>0Thank You