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Yogita Ingle 5 years, 9 months ago
Factors affecting crystal field splitting energy:
1) The coordination geometry and number of ligands around the metal ion- Generally, the tetrahedral field produce smaller spilling than octahedral field.
2) The nature of the ligands - Strong field ligands cause more splitting than weak field ligands.
3) The oxidation state of metals- Higher is the oxidation state of the central metal ion, greater is the crystal field splitting.
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Yogita Ingle 5 years, 9 months ago
The crystal field theory was proposed by Hans Bethe and VanVleck. This theory gives satisfactory explanation for the bonding and the properties of complexes than the valence bond theory.
Assumptions of Crystal field theory:
The interaction between the metal ion and the ligand is purely electrostatic.
Negative ligands are treated as point charges and neutral ligands are treated as dipoles.
The five d-orbitals in an isolated gaseous metal atom (or) ion are degenerate.
The repulsions between the electrons in the metal ion and the ligands increases the energy of the d-orbitals and lifts the degeneracy in d-orbitals. This results in the d- orbitals getting split.
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Shefu ??????? 5 years, 9 months ago
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