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Why free rotation about a sigma …

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Why free rotation about a sigma bond is not possible??

    • Posted by Yug Patel 3 years, 11 months ago

    CBSE > Class 11 > Chemistry
    • 1 answers

    Yogita Ingle 3 years, 11 months ago

    Free rotation around a bond is possible when the bond is formed by linear overlap.  Hence  there is free rotation around a sigma bond. There is no free rotation around a bond formed by parallel overlap.  Thus, there is no free rotation around a pi-bond.

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