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How can be mixture of o-nitrophenol …

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How can be mixture of o-nitrophenol and p-nitrophenol separated ?

Posted by Pushpender Singh 5 years, 8 months ago

CBSE > Class 11 > Chemistry

1 answers

Nikhil Kumar 5 years, 8 months ago

While separating a mixture of ortho and para nitrophenols by steam distillation, o-nitrophenol will be steam volatile due to presence of intramolecular hydrogen bonds. In case of p-nitrophenol, intermolecular hydrogen bonding is present which results in strong association of molecules. Hence, p-nitrophenol is not steam volatile.

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