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SiCl4 is easily hydrolysed but CCl4is …

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SiCl4 is easily hydrolysed but CCl4is not

Posted by Archit Gangwar 6 years, 8 months ago

CBSE > Class 11 > Chemistry

1 answers

Yogita Ingle 6 years, 8 months ago

CCl₄ doesnot undergo hydrolysis by water because the carbon atom is small and is shielded by larger chlorine atoms.
Carbon does not have 3d atomic orbitals that water can use to form co-ordinate bonds.
In SiCl₄, the silicon atom is larger than the carbon atom and also has available 3d atomic orbitals for bonding, thus hydrolysis is possible.

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