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Explain in brief (a) Anions are …

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Explain in brief (a) Anions are bigger in size than their parent atom. (B) oxygen has lesser first ionisation enthalpy. (c) fluorine has less negative electron gain enthalpy than chlorine.
  • 1 answers

Yogita Ingle 6 years, 8 months ago

c) Even though Fluorine has the highest electronegativity among all the  elements and it should have the highest electron gain enthalpy among all  the halogens but  this is an exception and chlorine has higher electron gain enthalpy than Fluorine.   The reason for this is that the size of Fluorine atom is very small and  hence there is very high inter-electronic repulsion among the electrons  of fluorine.  This makes incoming of another electron not very favourable.  Even though fluorine has large negative electron gain enthalpy but for chlorine its even more negative.

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