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How can you explain higher stability …

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How can you explain higher stability of Bcl3 as compared to TLcl3??

Posted by ???. Pragati 6 years, 11 months ago

CBSE > Class 11 > Chemistry

2 answers

Vaibhav Kumar Gupta 6 years, 11 months ago

Because both boron and chlorine are of small size and also of comparable size with each other , hence due to almost comparable size bond formed is more stable , as compared to bond foed between Thallium and chlorine where size/radius difference is more, hence in case of thallium weaker bond is formeand less stable.

Ankit Singh 6 years, 11 months ago

bcl3 is stable while ticl3 is unstable . Boron and thallium belong to group 13 of the periodic table. In this group, the +1 oxidation state becomes more stable on moving down the group. BCl 3 is more stable than TlCl 3 because the +3 oxidation state of B is more stable than the +3 oxidation state of Tl. Please confirm that my answer is correct .......

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