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Amar Kumar 8 years, 2 months ago
Some crystalline solids are anisotropic because despite showing periodicity they are not exactly the same in all directions. It all depends on the symmetry of the unit cell of the crystal. If its size in the x, y and z direction is the same, it would be isotropic and anisotropic otherwise.
All crystalline solids are not anisotropic. Those crystalline solids which are anisotropic, have their atoms arranged and spaced in a different manner in three different planes (X, Y and Z).Therefore, if light is passed through such crystal, it will experience different environments in different directions and hence different refractive indices will be obtained.
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The inert pair effect is the tendency of the electrons in the outermost atomic s orbital to remain unionized or unshared in compounds of post-transition metals.
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An ambident nucleophile is an anionic nucleophile whose negative charge is delocalized by resonance over two unlike atoms or over two like but non-equivalent atoms. The most common ambident nucleophiles are enolate ions.
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A catalytic reaction which depends upon the pore structure of the catalyst and on the size of the reactant and the product molecules is called shape-selective catalysis. For example, catalysis by zeolites is a shape-selective catalysis. The pore size present in the zeolites ranges from 260-740 pm. Thus, molecules having a pore size more than this cannot enter the zeolite and undergo the reaction.
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Aniket Garg 8 years, 2 months ago
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