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Amar Kumar 8 years, 1 month ago
Zn act as a reducing agent in the extraction of Ag. Reducing agent is a substance that tends to bring about reduction by being oxidized and losing electrons. Zinc is a chemical element with symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. In some respects zinc is chemically similar to magnesium,both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes.
Posted by Ruopfuno Zashumo 8 years, 1 month ago
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Amar Kumar 8 years, 1 month ago
In Chemisorption:With initial rise in temperature, the rate of adsorption increases but with further rise in temperature, after a certain limit, adsorption starts decreasing. This is because an initial rise in temperature will provide the molecules necessary activation energy for chemical bond formation so rate of adsorption increases. At a certain temperature all the bonds are formed and now the further increase in temperature will favourdesportion i.e., rate the adsorption now starts decreasing.
Chemical adsorption or Chemisorption: If the adsorbate molecules are bound to the surface of adsorbent by chemical bonds, the adsorption is known as chemical adsorption or chemisorption.
Effect of temperature: Even though chemical adsorption is an exothermic process, it does not occurs slowly at lower temperature due to high kinetic energy barrier. Hence, like most chemical changes, the extent of chemisorption increases with increase in temperature up to certain limit and then after that it starts decreasing.
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In the presence of sulphuric acid (H2SO4), KI produces HI
2KI + H2SO4 → 2KHSO4 + 2HI
Since H2SO4 is an oxidizing agent, it oxidizes HI (produced in the reaction to I2).
2HI + H2SO4 → I2 + SO2 + H2O
As a result, the reaction between alcohol and HI to produce alkyl iodide cannot occur. Therefore, sulphuric acid is not used during the reaction of alcohols with KI. A non-oxidizing acid such as H3PO4 is used.
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