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Ask QuestionPosted by Hetav Panchal 4 years, 10 months ago
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Posted by Namandeep Gupta 4 years, 10 months ago
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All Rounder Mkjha 4 years, 10 months ago
Vyakhya Gupta 4 years, 10 months ago
Yogita Ingle 4 years, 10 months ago
Aniline is an aromatic amine and it has a benzene ring which is electron withdrawing in nature. Because of this, the lone pair of electrons on nitrogen is not readily available for donation, as it is involved in the resonance. whereas methylamine is an aliphatic amine and the methyl group is electron donating in nature so the lone pair of nitrogen in methylamine is easily available for donation because there is no resonance in methyl amine.Thus methyl amine is more basic than aniline.
Posted by Baliyan ? 4 years, 10 months ago
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Abhijeet Pratap Singh 4 years, 10 months ago
Yogita Ingle 4 years, 10 months ago
Aldehydes: Aldehydes are the organic compounds in which carbonyl group is attached to one hydrogen atom and one alkyl or aryl group.
Posted by Prachi Rajput 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
i. Macromolecular sol: They are molecules of large size having high molecular masses. Due to long chain, the vander waal's forces are stronger, e.g., rubber, nylon etc.
ii. Peptization is the process responsible for the formation of stable dispersion of colloidal particles in dispersion medium. In other words, it may be defined as a process of converting a precipitate into colloidal sol by shaking it with dispersion medium in the presence of small amount of electrolyte.
iii. Emulsion is a fine dispersion of minute droplets of one liquid in another in which it is not soluble or miscible, e.g. milk.
Posted by Kirti Sharma? 4 years, 10 months ago
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Abhijeet Pratap Singh 4 years, 10 months ago
Jagdish Suthar 4 years, 10 months ago
Posted by Lalit Kumar 4 years, 10 months ago
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Posted by Srashtika Barode 4 years, 10 months ago
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Nishant Pandey 4 years, 10 months ago
Posted by Sneha Kakadiya 4 years, 10 months ago
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Meghna Thapar 4 years, 10 months ago
The reaction of aldehydes and ketones with ammonia or 1º-amines forms imine derivatives, also known as Schiff bases (compounds having a C=N function). Water is eliminated in the reaction, which is acid-catalyzed and reversible in the same sense as acetal formation. Two of the more important derivatives of ammonia are hydrazine and hydroxylamine. In strongly acidic medium ammonia derivatives being basic will react with acids and will not react with carbonyl compound. In basic medium, OH will attack carbonyl group. Hence pH of a reaction should be carefully controlled.
Posted by Sneha Kakadiya 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
Iodoform test is used to check the presence of carbonyl compounds with the structure R-CO-CH3 or alcohols with the structure R-CH(OH)-CH3 in a given unknown substance.
When Iodine and sodium hydroxide are added to a compound that contains either a methyl ketone or a secondary alcohol with a methyl group in the alpha position, a pale yellow precipitate of iodoform or triiodomethane is formed. It can be used to identify aldehydes or ketones. If an aldehyde gives a positive iodoform test, then it must be acetaldehyde since it is the only aldehyde with a CH3C=O group. Given below are a few example reactions for positive iodoform tests.
Posted by Dimpal Bhedi 4 years, 10 months ago
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Sneha Kakadiya 4 years, 10 months ago
Yogita Ingle 4 years, 10 months ago
Dehydrohalogenation of secondary- and tertiary-alkyl halides involves removal of the ?-hydrogen from the carbon that has the smallest number of hydrogens. This is Saytzeff rule.
According to this rule, major product is the most substituted alkene i.e., major product is obtained by elimination of H from that ?-carbon which has the least number of hydrogen. Product of the reaction in this case is known as Saytzeff product.
(ii) Hofmann rule : According to this rule, major product is always least substituted alkene i.e., major product is formed from ?-carbon which has maximum number of hydrogen. Product of the reaction in this case is known as Hofmann product.
Dehydrohalogenation of secondary- and tertiary-alkyl halides involves removal of the ?-hydrogen from the carbon that has the smallest number of hydrogens. This is satzeff rule.
Posted by Harshit Tiwari 4 years, 10 months ago
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Posted by Tarun Gautam 4 years, 10 months ago
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Posted by Akhilesh Yadav 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
SN1 | SN2 |
The rate of reaction is unimolecular. | The rate of reaction is bimolecular |
It is a two-step mechanism | It is only a one-step mechanism |
Carbocation is formed as an intermediate part of the reaction. | No carbocation is formed during the reaction. |
There is no partial bond formed with the carbon during this reaction. | Carbon forms a partial bond with the nucleophile and the leaving group. |
There are many steps in this reaction which start with the removal of the group while attacking the nucleophile. | The process takes place in only one cycle, with a single intermediate stage. |
Posted by Deepak Baranwal 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
Schottky defect is a type of point defect or imperfection in solids which is caused by a vacant position that is generated in a crystal lattice due to the atoms or ions moving out from the interior to the surface of the crystal.
A Frenkel defect is another form of a point defect which is created when an atom or cation leaves its original place in the lattice structure to create a vacancy while occupying another interstitial position within the solid crystal.
Yogita Ingle 4 years, 10 months ago
In Schottky defect the difference in size between cation and anion is small. Frenkel defect contains ionic crystals where the anion is larger than the cation. Both anion and cation leave the solid crystal. Usually the smaller ion cation leaves its original lattice structure. Atoms permanently leave the crystal.
Sahil Kumar 4 years, 10 months ago
Posted by Bala Murugan 4 years, 10 months ago
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Posted by Babita Dhankar 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
According to the valence bond theory, Electrons in a molecule occupy atomic orbitals rather than molecular orbitals. The atomic orbitals overlap on the bond formation and the larger the overlap the stronger the bond. The metal bonding is essentially covalent in origin and metallic structure involves resonance of electron-pair bonds between each atom and its neighbors.
Posted by Baliyan ? 4 years, 10 months ago
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Abhijeet Pratap Singh 4 years, 10 months ago
Baliyan ? 4 years, 10 months ago
Abhijeet Pratap Singh 4 years, 10 months ago
Posted by Hariom Pandit 4 years, 10 months ago
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Tanya ?? 4 years, 10 months ago
Hariom Pandit 4 years, 10 months ago
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Posted by Sushmita Kaushik 4 years, 10 months ago
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Posted by Nitish Kumar Mallick 4 years, 10 months ago
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Arjit Kumar 4 years, 10 months ago
Posted by Somal Brar 4 years, 10 months ago
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Meghna Thapar 4 years, 10 months ago
Calcium chloride is strongly hygroscopic (absorbs water from its surroundings), so it removes moisture from the air, making it dryer. This results in water in the substance to be dried to evaporate into the drier air, and this cycle repeats until the system reaches an equilibrium. Anhydrous calcium chloride is an inorganic salt that easily forms hydrates which promotes its use for removing water from any organic solution.
Posted by Jaideep Maan Maan 4 years, 10 months ago
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Posted by Bana J 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
Sulphur sol and gold sol are Lyophobic sols and are unstable and are build to colloidal size from small particles by the Condensation method by Chemical reactions.
Oxidation sulphur sol is prepared by passing H2S into SO2
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H2S + SO2 → S (sol) + H2O
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Reduction of AuCl3 with formaldehyde gives gold sol.
AuCl3+ HCHO + 3H2O → Au (sol) + 3HCOOH + 6HCl
Posted by Supriya Mahant 4 years, 10 months ago
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Aaditya Kushwah 4 years, 10 months ago
Posted by Dgf Chd 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
Transition elements (also known as transition metals) are elements that have partially filled d orbitals. IUPAC defines transition elements as an element having a d subshell that is partially filled with electrons, or an element that has the ability to form stable cations with an incompletely filled d orbital.
In general, any element which corresponds to the d-block of the modern periodic table (which consists of groups 3-12) is considered to be a transition element. Even the f-block elements comprising the lanthanides and the actinides can be considered as transition metals.
However, since the f-block elements have incompletely filled f-orbitals, they are often referred to as inner transition elements or inner transition metals. An illustration detailing the position of transition metals on the periodic table along with their general electronic configurations is provided below.
Posted by Dgf Chd 4 years, 10 months ago
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Meghna Thapar 4 years, 10 months ago
A block of the periodic table is a set of elements unified by the orbitals their valence electrons or vacancies lie in. The term appears to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-block, p-block, d-block, and f-block.
The block names (s, p, d, and f) are derived from the spectroscopic notation for the value of an electron's azimuthal quantum number: shape (0), principal (1), diffuse (2), or fundamental (3). Succeeding notations proceed in alphabetical order, as g, h, etc.
Posted by Dgf Chd 4 years, 10 months ago
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Meghna Thapar 4 years, 10 months ago
Transition metals share many similar properties including: They can form many compounds with different oxidation states. They can form compounds with different colors. They are metals and conduct electricity. Properties of transition elements include:
- have large charge/radius ratio;
- are hard and have high densities;
- have high melting and boiling points;
- form compounds which are often paramagnetic;
- show variable oxidation states;
- form coloured ions and compounds;
- form compounds with profound catalytic activity;
Subsequently, question is, why do all metals have similar properties? The reason that that elements in the same 'group' have similar chemical properties is because they have the same number of valence electrons. Iron when reacting in chemical reactions loses electrons from its 4s orbital instead of its d orbital.
Posted by Dgf Chd 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
As discussed earlier, the elements zinc, cadmium, and mercury are not considered transition elements since their electronic configurations are different from other transition metals. However, the rest of the d-block elements are somewhat similar in properties and this similarity can be observed along each specific row of the periodic table. These properties of the transition elements are listed below.
- These elements form coloured compounds and ions. This colour is explained by the d-d transition of electrons.
- There is a relatively low gap in energy between the possible oxidation states of these elements. The transition elements, therefore, exhibit many oxidation states.
- Many paramagnetic compounds are formed by these elements, because of the unpaired electrons in the d orbital.
- A large variety of ligands can bind themselves to these elements. Due to this, a wide variety of stable complexes are formed by transition elements.
- These elements have a large ratio of charge to the radius.
- Transition metals tend to be hard and they have relatively high densities when compared to other elements.
- The boiling points and the melting points of these elements are high, due to the participation of the delocalized d electrons in metallic bonding.
- This metallic bonding of the delocalized d electrons also causes the transition elements to be good conductors of electricity.
Posted by Dgf Chd 4 years, 10 months ago
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Yogita Ingle 4 years, 10 months ago
Zn, Cd, Hg are not regarded as transition element Because they have the completely filled d-sub-shell with outer electronic configuration (n-1)d10ns2
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Gaurav Seth 4 years, 10 months ago
Magnetic separation: This method is based on the magnetic and non-magnetic properties of the ore components
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