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Yogita Ingle 7 years ago
In chlorobenzene, the chlorine atom is attached to sp2 chybridized carbon atom. In cyclohexyl chloride, the chlorine atom is attached to sp3 hybridized carbon atom. Hence chlorobenzene is more electro negative than cyclohexyl chloride. Therefore, the density of electrons C-Cl bond at chlorine atom is less in chlorobenzene than cyclohexyl chloride. Due to this polarity of the C-Cl bond decreases and hence dipole moment of chlorobenzene is lower than cyclohexyl chloride.
Posted by Yashveer Chauhan 7 years ago
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Yogita Ingle 7 years ago
Conductivity changes with the concentration of the electrolyte. The number of ions per unit volume carrying the current decreases on dilution, so conductivity always decreases with decrease in concentration.
However, molar conductivity increases with dilution. This is because conductivity of a solution is the conductance of one unit volume of the solution, but molar conductivity is the conductance of that volume solution containing one mole of electrolyte.
As the total volume of solution containing one mole of electrolyte increases, the decrease in conductivity due to dilution is more than compensated by increase in its volume of solution that contains one mole of the electrolyte.
Posted by Rahul Guleria 7 years ago
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Yogita Ingle 7 years ago
A pure semiconductor, free from impurities is called intrinsic semiconductor
- The electrical conductivity of pure semiconductor is called intrinsic conductivity
- Structure – Consider pure Germanium and Silicon. Both have 4 valence electrons
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Yogita Ingle 7 years ago
The Krafft temperature is defined as the minimum temperature at which ionic surfactants, form micells. It depends on the nature of hydrophobic groups and ionic composition of the detergent.
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Yogita Ingle 7 years ago
AgBr shows both Frenkel and Schottky defects because the radius ratio for AgBr is intermediate.
Explaination:
Ions have Schottky defects when their anions and cations are both absent from the crystal lattice.
In AgBr, the Ag+ ions and corresponding Br̶̶‒ ions are absent from the crystal lattice causing Schottky defects.
However, Ag+ ions are exceptionally mobile and they have a tendency to move about inside the lattice. So they complement the Schottky defects with Frenkel defects with the Ag+ ions trapped in interstitial spaces. Because of the similar size of Ag+ ions and Br‒ ions and the small size of Ag+ ions and the fact that Ag+ ions have a property to be mobile, both Schottky and Frenkel defects occur.
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Yogita Ingle 7 years ago
Covalent compounds are the ones having strong intra-molecular bonds. This is because the atoms within the covalent molecules are very tightly held together. Each molecule is indeed quite separate and the force of attraction between the individual molecules in a covalent compound tends to be weak. Covalent compounds usually have low melting points. An exception to this include molecules of silica and diamonds that have a high melting point.
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