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Yogita Ingle 6 years, 10 months ago
- Freezing point of a substance is the temperature at which the vapour pressure
of the substance in its liquid phase is equal to the vapour pressure in the solid phase. - If the vapour pressure of the solution is equal to the vapour pressure of the pure solid solvent then the solution freezes.
- According to Raoult’s law, addition of non-volatile solute decreases the vapour pressure of the solvent and would be equal to that of solid solvent at lower This decreases the freezing point of thesolvent.
- The decrease in the freezing point = ΔTf = Tf – Tf0. This is known as depression in freezing point.
Tf0 = freezing point of pure solvent
Tf0 = freezing point when non-volatile solute is dissolved
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Gaurav Seth 6 years, 10 months ago
Basically NH₃ is a base due to the lone pair of electrons present on the Nitrogen atom which is available for donation. On the other hand PH₃ is also a base but its basic character is less than that of NH₃ because the nitrogen in phosphorous have lone pair of electrons that are not readily available for donation.
Also the P-H bonds are weaker than N-H bonds, so there’s not as much compensation for protonating PH₃. This is a result of the inert pair effect, seen in heavier elements.
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Gaurav Seth 6 years, 10 months ago
Alkyl Magnesium halides are called Grignard reagents (RMgX). Grignard reagents on reaction with Carbonyl compounds forms alcohols. 
Grignard reagent on reaction with formaldehyde forms primary alcohol.Grignard reagent on reaction with aldehydes forms secondary alcohols.Grignard reagent on reaction with ketones forms tertiary alcohols. 
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Neha ?? 6 years, 10 months ago
2Thank You